brandenhill4407 brandenhill4407
  • 19-05-2018
  • Chemistry
contestada

Write the mechanism of the reaction of methyl benzoate to form methyl 2-nitrobenzoate.

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PBCHEM
PBCHEM PBCHEM
  • 29-05-2018
The question is incorrect, nitration of methylbenzoate occurs at 3 position to get, methyl 3-nitrobenzoate. 

This is because, in present reaction the reactant i.e. methylbenzoate, has low electron density at m-position.

Due to this, NO2+ prefentially attaches m-position to form  methyl 3-nitro benzoate as the product. 

A detailed reaction mechanism for formation of product is provided below.

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